Beyond Amphiphilicity - RTG 2670: Self-Organization of Soft Matter via Multiple Noncovalent Interactions
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B1: Thermodynamics of fluorophilicity, lipophilicity, hydrophilicity, and their combination in polymers
An important aspect of polymers with fluorinated groups is their potential triphilic character, i.e. they have in addition to hydrophilic and lipophilic building blocks also fluorophilic units. Syntheses and characterization of their self-assembly in bulk and in selective solvents, as well as their potential applications are thus a core contribution to the planned RTG.
Here, we focus on syntheses of semi-telechelic polymers with fluorophilic units and the description of their behavior in selective solvents based on binary partition coefficients. These data allow for conclusions on the self-assembly of triphilic polymers.
An important aspect of polymers with fluorinated groups is their potential triphilic character, i.e. they have in addition to hydrophilic and lipophilic building blocks also fluorophilic units. Syntheses and characterization of their self-assembly in bulk and in selective solvents, as well as their potential applications are thus a core contribution to the planned RTG.
Here, we focus on syntheses of semi-telechelic polymers with fluorophilic units and the description of their behavior in selective solvents based on binary partition coefficients. These data allow for conclusions on the self-assembly of triphilic polymers.
Kontakt
Prof. Dr. Jörg Kreßler
Martin-Luther-Universität Halle-Wittenberg
Naturwissenschaftliche Fakultät II
Von-Danckelmann-Platz 4
06120
Halle (Saale)
Tel.:+49 345 5525800
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